Webber va fi urmat de coechipierul său Sebastian Vettel, de Lewis Hamilton (McLaren-Mercedes), Fernando Alonso (Ferrari) şi de Jenson Button (McLaren-Mercedes).
Grila de start a Marelui Premiu de Formula 1 al Spaniei este următoarea:
1. Mark Webber (Austria/Red Bull-Renault) 1:20.981
2. Sebastian Vettel (Germania/Red Bull-Renault) 1:21.181
3. Lewis Hamilton (Marea Britanie/McLaren-Mercedes) 1:21.961
4. Fernando Alonso (Spania/Ferrari) 1:21.964
5. Jenson Button (Marea Britanie/McLaren-Mercedes) 1:21.996
6. Vitali Petrov (Rusia/Lotus-Renault) 1:22.471
7. Nico Rosberg (Germania/Mercedes) 1:22.599
8. Felipe Massa (Brazilia/Ferrari) 1:22.888
9. Pastor Maldonado (Venezuela/Williams-Cosworth) 1:22.952
10. Michael Schumacher (Germania/Mercedes) 1:22.671
11. Sebastien Buemi (Elveţia/Toro Rosso-Ferrari) 1:23.231
12. Sergio Perez (Mexic/Sauber-Ferrari) 1:23.367
13. Jaime Alguersuari (Spania/Toro Rosso-Ferrari) 1:23.694
14. Kamui Kobayashi (Japonia/Sauber-Ferrari) 1:23.702
15. Heikki Kovalainen (Finlanda/Team Lotus) 1:25.403
16. Paul di Resta (Marea Britanie/Force India-Mercedes) 1:26.126
17. Adrian Sutil (Germania/Force India-Mercedes) 1:26.571
18. Jarno Trulli (Italia/Team Lotus) 1:26.521
19. Rubens Barrichello (Brazilia/Williams-Cosworth) 1:26.910
20. Timo Glock (Germania/Virgin-Cosworth) 1:27.315
21. Vitantonio Liuzzi (Italia/Hispania-Cosworth) 1:27.809
22. Narain Karthikeyan (India/Hispania-Cosworth) 1:27.908
23. Jerome d’Ambrosio (Belgia/Virgin-Cosworth) 1:28.556
24. Nick Heidfeld (Germania/Lotus-Renault) fără timp în Q1.